Baldwin's rules: 20 favored / 10 disfavored of 30 (n, mode, hyb) triples

Layer 2 — Chemistryin the natural-product-chemistry subtree

Baldwin's rules (J. E. Baldwin, J. Chem. Soc. Chem. Commun. 1976, 734): empirical stereo-electronic preferences for ring-closure reactions, classified by a three-parameter tuple: ring size n ∈ {3, 4, 5, 6, 7}, mode ∈ {exo (breaking bond…

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