Microscopic picture underlying the Langmuir isotherm: adsorption is a reversible reaction A(gas) + site(surface) ⇌ A·site with a single rate constant each way. Steady-state treatment yields θ = Kp/(1+Kp). Extends to competitive…
Microscopic picture underlying the Langmuir isotherm: adsorption is a reversible reaction A(gas) + site(surface) ⇌ A·site with a single rate constant each way. Steady-state treatment yields θ = Kp/(1+Kp). Extends to competitive…