Lindemann unimolecular limits: low-[M] leading term = k₁·[M]; high-[M] asymptote = k₁·k₂/k₋₁ = k_∞

Layer 2 — Chemistryin the reaction-dynamics subtree

Pressure-limit evaluations: k_uni low-[M] leading term is k₁·[M] (activation-limited, linear in [M]); k_uni high-[M] limit is k₁·k₂/k₋₁ (first-order, independent of [M]). Canonical pins: full k_uni symbolic form; low-[M] leading Taylor…

Related concepts

Lindemann-Hinshelwood unimolecular framework: k_uni = k₁·k₂·[M]/(k₋₁·[M] + k₂) (fall-off between 2nd and 1st order)
Partition function

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