Marcus 1956 (Nobel 1992): outer-sphere ET rate k_ET = ν_n κ exp(-ΔG*/k_BT) with ΔG* = (λ + ΔG°)²/(4λ); inverted-region prediction λ < |ΔG°|. Beratan-Onuchic extension to biological ET (cytochrome / photosynthesis). Bridges chemistry to…
Marcus 1956 (Nobel 1992): outer-sphere ET rate k_ET = ν_n κ exp(-ΔG*/k_BT) with ΔG* = (λ + ΔG°)²/(4λ); inverted-region prediction λ < |ΔG°|. Beratan-Onuchic extension to biological ET (cytochrome / photosynthesis). Bridges chemistry to…