Heme-iron, cytochrome-P450 reaction-cycles involve Fe(II/III) HS↔LS transitions modulated by axial ligand-field strength. Tanabe-Sugano diagrams predict crossover field B = 10Dq_crit. Mössbauer-isomer-shift, magnetic-susceptibility,…
Heme-iron, cytochrome-P450 reaction-cycles involve Fe(II/III) HS↔LS transitions modulated by axial ligand-field strength. Tanabe-Sugano diagrams predict crossover field B = 10Dq_crit. Mössbauer-isomer-shift, magnetic-susceptibility,…